{"id":6770,"date":"2023-07-11T08:40:04","date_gmt":"2023-07-11T00:40:04","guid":{"rendered":"http:\/\/budcs.com\/?p=6770"},"modified":"2023-07-11T08:41:18","modified_gmt":"2023-07-11T00:41:18","slug":"246-%e4%b8%89%e7%a1%9d%e5%9f%ba%e7%94%b2%e8%8b%af%e5%ae%9e%e9%aa%8c%e5%ae%a4%e4%bd%bf%e7%94%a8%e6%b3%a8%e6%84%8f%e4%ba%8b%e9%a1%b9","status":"publish","type":"post","link":"http:\/\/www.budcs.com\/archives\/6770","title":{"rendered":"2,4,6-\u4e09\u785d\u57fa\u7532\u82ef\u5b9e\u9a8c\u5ba4\u4f7f\u7528\u6ce8\u610f\u4e8b\u9879"},"content":{"rendered":"

1. \u7a7f\u6234\u4e2a\u4eba\u9632\u62a4\u88c5\u5907\uff1a\u5728\u5b9e\u9a8c\u5ba4\u4e2d\u63a5\u89e62,4,6-\u4e09\u785d\u57fa\u7532\u82ef\u65f6\uff0c\u5fc5\u987b\u4f69\u6234\u9002\u5f53\u7684\u4e2a\u4eba\u9632\u62a4\u88c5\u5907\uff0c\u5305\u62ec\u5316\u5b66\u9632\u62a4\u670d\u3001\u9632\u62a4\u624b\u5957\u3001\u62a4\u76ee\u955c\u548c\u9632\u62a4\u9762\u7f69\u3002\u8fd9\u4e9b\u88c5\u5907\u53ef\u4ee5\u6709\u6548\u5730\u4fdd\u62a4\u76ae\u80a4\u548c\u773c\u775b\u4e0d\u53d7\u5316\u5b66\u7269\u8d28\u7684\u523a\u6fc0\u548c\u635f\u4f24\u3002<\/p>\n

2. \u4f7f\u7528\u901a\u98ce\u8bbe\u5907\uff1a2,4,6-\u4e09\u785d\u57fa\u7532\u82ef\u6325\u53d1\u6027\u8f83\u5927\uff0c\u6709\u5f3a\u70c8\u523a\u6fc0\u6027\u6c14\u5473\uff0c\u56e0\u6b64\u5e94\u5728\u5b9e\u9a8c\u5ba4\u4e2d\u8bbe\u7f6e\u826f\u597d\u7684\u901a\u98ce\u7cfb\u7edf\uff0c\u4ee5\u786e\u4fdd\u5ba4\u5185\u7a7a\u6c14\u8d28\u91cf\u3002\u5b9e\u9a8c\u5ba4\u8bbe\u5907\u4e0a\u7684\u6392\u98ce\u6247\u53ef\u4ee5\u5e2e\u52a9\u6392\u9664\u6709\u5bb3\u6c14\u4f53\u3002<\/p>\n

3. \u64cd\u4f5c\u6ce8\u610f\u4e8b\u9879\uff1a\u5728\u5904\u74062,4,6-\u4e09\u785d\u57fa\u7532\u82ef\u65f6\uff0c\u5e94\u8c28\u614e\u907f\u514d\u4ea7\u751f\u9759\u7535\u706b\u82b1\uff0c\u56e0\u4e3a\u5b83\u53ef\u80fd\u5f15\u53d1\u7206\u70b8\u3002\u5e94\u4f7f\u7528\u5de5\u5177\u548c\u8bbe\u5907\u8fdb\u884c\u64cd\u4f5c\uff0c\u907f\u514d\u76f4\u63a5\u63a5\u89e6\u5316\u5b66\u7269\u8d28\u3002<\/p>\n

4. \u907f\u514d\u4e0e\u5176\u4ed6\u7269\u8d28\u63a5\u89e6\uff1a2,4,6-\u4e09\u785d\u57fa\u7532\u82ef\u4e0e\u8bb8\u591a\u5176\u4ed6\u5316\u5b66\u7269\u8d28\uff08\u5982\u5f3a\u6c27\u5316\u5242\u3001\u9178\u548c\u78b1\uff09\u53ef\u80fd\u76f8\u4e92\u4f5c\u7528\uff0c\u4ea7\u751f\u5371\u9669\u7684\u5316\u5b66\u53cd\u5e94\u6216\u7206\u70b8\u3002\u5728\u5b9e\u9a8c\u5ba4\u4e2d\u5e94\u8be5\u907f\u514d\u4e0e\u8fd9\u4e9b\u7269\u8d28\u63a5\u89e6\u548c\u6df7\u5408\u3002<\/p>\n

5. \u5e9f\u5f03\u7269\u5904\u7406\uff1a\u5e9f\u5f03\u76842,4,6-\u4e09\u785d\u57fa\u7532\u82ef\u5e94\u88ab\u89c6\u4e3a\u5371\u9669\u5e9f\u7269\uff0c\u5e76\u4e14\u5fc5\u987b\u6309\u7167\u76f8\u5e94\u7684\u6cd5\u89c4\u8fdb\u884c\u59a5\u5584\u5904\u7406\u3002 \u5e94\u5c06\u5176\u50a8\u5b58\u5728\u4e13\u95e8\u8bbe\u8ba1\u7684\u5bb9\u5668\u4e2d\uff0c\u5e76\u4e0e\u6709\u8d44\u8d28\u7684\u5e9f\u7269\u5904\u7406\u516c\u53f8\u5408\u4f5c\uff0c\u786e\u4fdd\u5176\u5b89\u5168\u5904\u7406\u548c\u5904\u7f6e\u3002<\/p>\n

6. \u7d27\u6025\u60c5\u51b5\u5904\u7406\uff1a\u5982\u679c\u53d1\u751f\u6cc4\u6f0f\u3001\u6ce1\u6cab\u6216\u706b\u707e\u7b49\u7d27\u6025\u60c5\u51b5\uff0c\u5e94\u7acb\u5373\u91c7\u53d6\u9002\u5f53\u7684\u7d27\u6025\u5904\u7406\u63aa\u65bd\uff0c\u5305\u62ec\u5c06\u9644\u8fd1\u4eba\u5458\u64a4\u79bb\u5230\u5b89\u5168\u5730\u70b9\uff0c\u5e76\u5bfb\u6c42\u9075\u5faa\u5b9e\u9a8c\u5ba4\u7684\u5e94\u6025\u64cd\u4f5c\u7a0b\u5e8f\u3002<\/p>\n

\u6700\u91cd\u8981\u7684\u662f\uff0c\u5bf9\u4e8e2,4,6-\u4e09\u785d\u57fa\u7532\u82ef\u7b49\u5371\u9669\u5316\u5b66\u54c1\u7684\u64cd\u4f5c\u548c\u4f7f\u7528\uff0c\u5fc5\u987b\u9075\u5faa\u5b9e\u9a8c\u5ba4\u7684\u5b89\u5168\u64cd\u4f5c\u89c4\u7a0b\u548c\u6cd5\u89c4\u8981\u6c42\uff0c\u8fdb\u884c\u5145\u5206\u7684\u57f9\u8bad\u548c\u6307\u5bfc\uff0c\u5e76\u4fdd\u6301\u8b66\u60d5\u548c\u8c28\u614e\u3002<\/p>\n

2,4,6-\u4e09\u785d\u57fa\u7532\u82ef;\u68af\u6069\u68af;\u8336\u8910\u70b8\u836f;2,4,6-Trinitrotoluene;TNT
\n\u56fd\u6807\u7f16\u53f7 11035 CAS\u53f7 118-96-7 \u5206\u5b50\u5f0f C7H5N3O6;(NO2)3C6H2CH3 \u5206\u5b50\u91cf 227.13 \u767d\u8272\u6216\u82cb\u8272\u9488\u72b6\u7ed3\u6676\uff0c\u65e0\u81ed\uff0c\u6709\u5438\u6e7f\u6027;\u84b8\u6c7d\u538b0.01kPa(82\u2103);\u7194\u70b981.8\u2103;\u6cb8\u70b9280\u2103(\u7206\u70b8);\u6eb6\u89e3\u6027:\u4e0d\u6eb6\u4e8e\u6c34\uff0c\u5fae\u6eb6\u4e8e\u4e59\u9187\uff0c\u6eb6\u4e8e\u82ef\u3001\u82b3\u70c3\u3001\u4e19\u916e;\u5bc6\u5ea6:\u76f8\u5bf9\u5bc6\u5ea6(\u6c34=1)1.65;\u7a33\u5b9a\u6027:\u7a33\u5b9a;\u5371\u9669\u6807\u8bb0 1(\u7206\u70b8\u54c1);\u4e3b\u8981\u7528\u9014:\u7528\u4e8e\u5236\u9020\u67d3\u6599\u3001\u533b\u836f\u3001\u70b8\u836f\uff0c\u4e5f\u4f5c\u8bd5\u5242\u7b49
\n2.\u5bf9\u73af\u5883\u7684\u5f71\u54cd: \u4e00\u3001\u5065\u5eb7\u5371\u5bb3
\n\u4fb5\u5165\u9014\u5f84\uff1a\u5438\u5165\u3001\u98df\u5165\u3001\u7ecf\u76ae\u5438\u6536\u3002 \u5065\u5eb7\u5371\u5bb3\uff1a\u5c5e\u9ad8\u5ea6\u5371\u5bb3\u6bd2\u7269\u3002\u5bf9\u8840\u6db2\u7cfb\u7edf\u7684\u635f\u5bb3\uff0c\u53ef\u5f62\u6210 \u9ad8\u94c1\u8840\u7ea2\u86cb\u767d\u3001\u8d6b\u6c0f\u5c0f\u4f53;\u53ef\u5f15\u8d77\u4e2d\u6bd2\u6027\u809d\u635f\u4f24;\u5bf9\u773c\u775b\u53ef\u5f15\u8d77\u4e2d\u6bd2\u6027\u767d\u5185\u969c\u3002 \u6025\u6027\u4e2d\u6bd2\uff1a\u8f7b\u5ea6\u8005\u5934\u6655\u3001\u5934\u75db\u3001\u6076\u5fc3\u3001\u5455\u5410\u3001\u8179\u75db\u3001\u53d1\u7ec0\u7b49;\u91cd\u75c7\u8005\u795e\u5fd7\u4e0d\u6e05\u3001\u547c\u5438\u8868\u6d45\u3001\u5927\u5c0f\u4fbf\u5931\u7981\u3001\u77b3\u5b54\u6563\u5927\u3001\u89d2\u819c\u53cd\u5c04\u6d88\u5931\uff0c\u53ef\u56e0\u547c\u5438\u9ebb\u75f9\u800c\u6b7b\u4ea1\u3002 \u6162\u6027\u4e2d\u6bd2\uff1a\u53ef\u53d1\u751f\u4e2d\u6bd2\u6027\u767d\u5185\u969c\u3001\u4e2d\u6bd2\u6027\u809d\u708e\u3001\u8d2b\u8840\u3001\u76ae\u708e\u3001\u6e7f\u75b9\u3002\u957f\u671f\u63a5\u89e6\u53ef\u51fa\u73b0\u201cTNT\u201d\u9762\u5bb9\uff1a\u9762\u90e8\u82cd\u767d\uff0c\u53e3\u5507\u3001\u8033\u5ed3\u7d2b\u7ec0\u3002
\n\u4e8c\u3001\u6bd2\u7406\u5b66\u8d44\u6599\u53ca\u73af\u5883\u884c\u4e3a
\n\u6bd2\u6027\uff1a\u5c5e\u4e2d\u7b49\u6bd2\u6027\u3002 \u6025\u6027\u6bd2\u6027\uff1aLD50795mg\/kg(\u5927\u9f20\u7ecf\u53e3);660mg\/kg(\u5c0f\u9f20\u7ecf\u53e3)\u4eba\u5438\u51652mg\/m3\u8840\u6db2\u8f7b\u5ea6\u6539\u53d8;\u4eba\u7ecf\u53e31mg\/kg\u00d74\u65e5\u672a\u89c1\u8840\u6db2\u5b66\u6539\u53d8;\u4eba\u5728>2mg\/m3\u73af\u5883\u4e2d\u6709\u4e0d\u60a6\u611f\u3002
\n\u5371\u9669\u7279\u6027\uff1a\u53d7\u70ed\uff0c\u63a5\u89e6\u660e\u706b\u3001\u9ad8\u70ed\u6216\u53d7\u5230\u6469\u64e6\u9707\u52a8\u3001\u649e\u51fb\u65f6\u53ef\u53d1\u751f\u7206\u70b8\u3002
\n\u71c3\u70e7(\u5206\u89e3)\u4ea7\u7269\uff1a\u4e00\u6c27\u5316\u78b3\u3001\u4e8c\u6c27\u5316\u78b3\u3001\u6c27\u5316\u6c2e\u3002
\n3.\u73b0\u573a\u5e94\u6025\u76d1\u6d4b\u65b9\u6cd5:
\n\u5e9f\u6c34\u4e2d2\uff0c4\uff0c6-\u4e09\u785d\u57fa\u7532\u82ef\u7684\u79bb\u5b50\u4ea4\u6362\u6811\u8102\u73b0\u573a\u68c0\u6d4b-(Heller,Carl A.;Greni,Sterling
\nR.;Erickson,Eric D.),\u300aAnal.Chem.\u300b,1982,54,No2,286\uff5e289(\u82f1\u6587)\u300a\u5206\u6790\u5316\u5b66\u6587\u6458\u300b1983.10
\n4.\u5b9e\u9a8c\u5ba4\u76d1\u6d4b\u65b9\u6cd5:
\n\u6c14\u76f8\u8272\u8c31\u6cd5(GB\/T13904-92\uff0c\u6c34\u8d28)
\n\u4e9a\u786b\u9178\u94a0\u5206\u5149\u5149\u5ea6\u6cd5(GB\/T13905-92\uff0c\u6c34\u8d28)
\n\u6c14\u76f8\u8272\u8c31\u6cd5;\u4e59\u9187-\u78b1\u6bd4\u8272\u6cd5\u300a\u7a7a\u6c14\u4e2d\u6709\u5bb3\u7269\u8d28\u7684\u6d4b\u5b9a\u65b9\u6cd5\u300b(\u7b2c\u4e8c\u7248)\uff0c\u676d\u58eb\u5e73\u7f16
\n5.\u73af\u5883\u6807\u51c6:
\n\u4e2d\u56fd(TJ36-79) \u8f66\u95f4\u7a7a\u6c14\u4e2d\u6709\u5bb3\u7269\u8d28\u7684\u6700\u9ad8\u5bb9\u8bb8\u6d53\u5ea6 1mg\/m3 [\u76ae]
\n\u4e2d\u56fd(\u5f85\u9881\u5e03) \u996e\u7528\u6c34\u6e90\u6c34\u4e2d\u6709\u5bb3\u7269\u8d28\u7684\u6700\u9ad8\u5bb9\u8bb8\u6d53\u5ea6 0.5mg\/L
\n\u4e2d\u56fd(GB4274-84) \u68af\u6069\u68af\u5de5\u4e1a\u6c34\u6c61\u67d3\u7269\u6392\u653e\u6807\u51c6 0.5\uff5e30.0mg\/L(\u603b\u785d\u57fa\u5316\u5408\u7269\uff0c\u4ee52,4-DNT \u548c\u03b1-DNT \u8ba1)
\n6.\u5e94\u6025\u5904\u7406\u5904\u7f6e\u65b9\u6cd5:
\n\u4e00\u3001\u6cc4\u6f0f\u5e94\u6025\u5904\u7406
\n\u9694\u79bb\u6cc4\u6f0f\u6c61\u67d3\u533a\uff0c\u5468\u56f4\u8bbe\u8b66\u544a\u6807\u5fd7\uff0c\u5207\u65ad\u706b\u6e90\u3002\u5efa\u8bae\u5e94\u6025\u5904\u7406\u4eba\u5458\u6234\u597d\u9632\u6bd2\u9762\u5177\uff0c\u7a7f\u5316\u5b66\u9632\u62a4\u670d\u3002
\n\u51b7\u5374\uff0c\u9632\u6b62\u9707\u52a8\u3001\u649e\u51fb\u548c\u6469\u64e6\uff0c\u907f\u514d\u626c\u5c18\uff0c\u4f7f\u7528\u65e0\u706b\u82b1\u5de5\u5177\u5c0f\u5fc3\u626b\u8d77\uff0c\u8f6c\u79fb\u5230\u5b89\u5168\u573a\u6240\u3002\u4e5f\u53ef\u4ee5\u7528\u5927\u91cf\u6c34\u51b2\u6d17\uff0c\u4ee5\u7a00\u91ca\u7684\u6d17\u6c34\u653e\u5165\u5e9f\u6c34\u7cfb\u7edf\u3002\u5982\u5927\u91cf\u6cc4\u6f0f\uff0c\u7528\u6c34\u6da6\u6e7f\uff0c\u7136\u540e\u6536\u96c6\u3001\u8f6c\u79fb\u3001\u56de\u6536\u6216\u65e0\u5bb3\u5904\u7406\u540e\u5e9f\u5f03\u3002
\n\u5e9f\u5f03\u7269\u5904\u7f6e\u65b9\u6cd5\uff1a\u7528\u711a\u70e7\u6cd5\u3002\u5e9f\u6599\u6eb6\u4e8e\u4e19\u916e\u540e\u518d\u711a\u70e7\uff0c\u711a\u70e7\u7089\u8981\u6709\u540e\u71c3\u70e7\u5ba4\uff0c\u711a\u70e7\u7089\u6392\u51fa\u7684\u6c27\u5316\u901a\u8fc7\u78b1\u6d17\u6da4\u5668\u9664\u53bb\u6709\u5bb3\u6210\u5206\u3002
\n\u4e8c\u3001\u9632\u62a4\u63aa\u65bd
\n\u547c\u5438\u7cfb\u7edf\u9632\u62a4\uff1a\u7a7a\u6c14\u4e2d\u6d53\u5ea6\u8f83\u9ad8\u65f6\uff0c\u4f69\u6234\u9632\u6bd2\u9762\u5177\u3002\u7d27\u6025\u4e8b\u6001\u62a2\u6551\u6216\u9003\u751f\u65f6\uff0c\u4f69\u6234\u81ea\u7ed9\u5f0f\u547c\u5438\u5668\u3002
\n\u773c\u775b\u9632\u62a4\uff1a\u6234\u5b89\u5168\u9632\u62a4\u773c\u955c\u3002
\n\u9632\u62a4\u670d\uff1a\u7a7f\u7d27\u8896\u5de5\u4f5c\u670d\uff0c\u957f\u7edf\u80f6\u978b\u3002
\n\u624b\u9632\u62a4\uff1a\u6234\u6a61\u76ae\u80f6\u624b\u5957\u3002
\n\u5176\u5b83\uff1a\u5de5\u4f5c\u73b0\u573a\u7981\u6b62\u5438\u70df\u3001\u8fdb\u98df\u548c\u996e\u6c34\u3002\u5de5\u4f5c\u540e\uff0c\u6dcb\u6d74\u66f4\u8863\u3002\u4fdd\u6301\u826f\u597d\u7684\u536b\u751f\u4e60\u60ef\u3002\u8fdb\u884c\u5c31\u4e1a\u524d\u548c
\n\u5b9a\u671f\u7684\u4f53\u68c0\u3002
\n\u4e09\u3001\u6025\u6551\u63aa\u65bd
\n\u76ae\u80a4\u63a5\u89e6\uff1a\u7acb\u5373\u8131\u53bb\u6c61\u67d3\u7684\u8863\u7740\uff0c\u7528\u80a5\u7682\u6c34\u53ca\u6e05\u6c34\u5f7b\u5e95\u51b2\u6d17\u3002
\n\u773c\u775b\u63a5\u89e6\uff1a\u7acb\u5373\u63d0\u8d77\u773c\u7751\uff0c\u7528\u5927\u91cf\u6d41\u52a8\u6e05\u6c34\u6216\u751f\u7406\u76d0\u6c34\u51b2\u6d17\u3002
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